Episode 3.03

“Chuck vs. the Angel de la Muerte”
Airdate: January 11, 2010
Gallery: Promotional Photos | Screencaps

Official Synopsis – added 01.02.10
Chuck ALWAYS PROTECTS HIS FAMILY FROM HIS SPY LIFE BUT CAN’T STOP Ellie AND AWESOME FROM STUMBLING INTO AN INTERNATIONAL INCIDENT—ARMAND ASSANTE (“AMERICAN GANGSTER”) GUEST STARS—Chuck (Zachary Levi) must use his relationship with Awesome (Ryan McPartlin) to protect a visiting dictator, Premier Goya (guest star Armand Assante), who is the target of an assassination. While Awesome is excited about the prospect of being a spy, Chuck (Zachary Levi) is more concerned about Awesome and Ellie’s (Sarah Lancaster) safety. Yvonne Strahovski and Adam Baldwin also star.

Spoilers – added 08.16.09
Features a character named Premier Allejandro Goya, the dictator of a fictitious South American nation called Parador. Goya has come to the U.S. to announce that his country will be holding open, Democratic elections for the first time. Will Team Bartowski be tasked with protecting the Premier? Or is his true motive for visiting the U.S. something more sinister?

Source: SpoilerTV